Bihar Polytechnic Lateral Entry Syllabus | PDF Download

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 15/04/2023

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Bihar Polytechnic Lateral Exam Syllabus

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SubjectsNo. of ChapterSyllabus
PhysicsTotal 24 TopicsCheck Syllabus
MathTotal 24 TopicsCheck Syllabus
Physical ChemistryTotal 24 TopicsCheck Syllabus
Organic ChemistryTotal 24 TopicsCheck Syllabus
Inorganic ChemistryTotal 24 TopicsCheck Syllabus

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Bihar Polytechnic Syllabus 2023

Bihar Polytechic Physics Important Topics (Lateral Entry)

01.Introduction and measurement
02.Mathematical Tools
03.Kinematics of Particles
04.Force and Laws of Motion
05.Work, Energy and Power
06.Rotation
07.Gravitation
08.Properties of Matter
09.Heat and thermodynamics
10.Oscillations
11.Waves and Acoustics
12.Universe
13.Ray Optics
14.Wave Optics
15.Electrostatics
16.Current Electricity
17.Thermal and Chemical effect of current
18.Magnetic effect of current
19.Electromagnetic Induction and Alternating Current
20.Magnetism
21.Electromagnetic waves (Qualitative treatment)
22.Atomic and Nuclear Physics
23.Semiconductor devices
24.Basics of Communication (Qualitative treatment)

Bihar Polytechic Physical Chemistry Topics (Lateral Entry)

01.Mole concept and related numerical analysis
02.Oxidation and reduction
03.States of matter
04.Atomic structure
05.Radioactivity
06.Chemical bonding
07.Acids, bases and salts
08.Volumetry
09.Energetics
10.Chemical and related equilibria
11.Colligative properties of solutions
12.Chemical Kinetics
13.Electrochemistry
14.Surface chemistry

Bihar Polytechic Organic Chemistry Topics (Lateral Entry)

01.Fundamentals
02.Isomerism
03.General concept
04.Principle
05.Polymer

Bihar Polytechic Inorganic Chemistry Topics (Lateral Entry)

01.Periodicity of elements
02.Transition elements
03.Metallurgy, Ores and minerals, gaugue, flux and slag
04.Chemistry of non metals and their compounds
05.Principles of qualitative analysis
06.Preparation of important compounds and their uses
07.Fertilizers
08.Pollution

Bihar Polytechic Math Topics (Lateral Entry)

01.Set Theory
02.Boolean Algebra
03.Mathematical Logic
04.Algebra
05.Quadratic equations and expressions
06.Matrices and Determinants
07.Trigonometry
08.Two Dimensional co-ordinate Geometry
09.Calculus
10.Differential Equations
11.Vectors
12.3-Dimensional co-ordinate geometry
13.Statics
14.Dynamics
15.Probability

DECE LE Physics Syllabus

1. Introduction and measurement

  • Science and scientific method, Physics and its relation with society, Technology and other branches of Science
  • Physics Quantities and their measurement units system of units, s.i. system, Fundamental and Derived Units.
  • Dimensions and their applications. Accuracy and Precision, Systematic and random errors. Gaussian distribution
  • for random errors. Standard deviation, RMS value, Combination of errors, Order of magnitude, Significant
  • figures, Rounding off.

2. Mathematical Tools

  • Scalar and vector quantities, vector addition and substruction, Unit vectors, Null vector Resolution method for
  • vector addition and subtraction, Scalar and vector Products. Concept of Differentiation and Integration as
  • applied in Physics. Cartesian Coordinate system. Graphs-plotting and interpreting. Interpretation of slopes of
  • chords and tangents, Curvature, Maxima and Minima, Area under a curve.

3. Kinematics of Particles

  • Concept of particles, Uniform rectilinear motion, Uniformly accelerated rectilinear motion-their graphical
  • representation, Freely falling bodies. Motion in two and three- dimensions. Projectile motion, Change of frame
  • and relative velocity.

4. Force and Laws of Motion

  • Interactions and Force, Basic idea about the fundamental forces of Nature (Gravitational, Electromagnetic
  • and Nuclear forces), Force and Motion : Newton’s first law of motion, Concurrent forces and equilibrium,
  • momentum, Inertial and Non-Inertial reference frames. Newton’s second law of motion, Impulse. Newton’s
  • third law of motion. Conservation of Linear momentum. Motion of connected bodies. Rocket propulsion, Static
  • and kinetic friction, Laws of friction, Rolling friction, Lubrication, motion on rough inclined surface, Uniform
  • circular motion, Centripetal force and acceleration, Centripetal force of a pseudo force, Banking of roads,
  • motion of vertical circle conical pendulum.

5. Work, Energy and Power

  • Work, Kinetic energy, Power, work energy theorem for system of particle, Internal and external forces,
  • Conservative and dissipative forces, potential Energy, Potential energy for simple systems like simple pendulum,
  • electron moving around nucleus, satellite, etc. Law of conservation of Energy, Equivalence of Mass and
  • Energy, Elastic collision in one and two dimensions, Inelastic collision in one dimension, Coefficient of restitution.

6. Rotation

  • Centre of mass for a two particle system, many particle system and for rigid body, Moment of Inertia and
  • Radius of Gyration-their physical significance, parallel axis theorem, Perpendicular axes theorem for a lamina,
  • calculation of moment of inertia of ring. Disk, rod rectangular bar and sphere, Torque, Couple, Equilibrium of
  • Rigid Bodies, Relation between Torque and angular acceleration, Angular momentum, Conservation, General
  • motion of rigid body in a plane ( Translation of centre of mass and Rotation about axis passing through centre
  • of mass), Motion of rolling bodies.

7. Gravitation

  • Newton’s law of Universal Gravitation, Inertial and Gravitational Mass, Gravitational potential and field, their
  • calculation for hollow and solid sphere, Acceleration due to gravity and its variation, kepler’s Laws of planetary
  • motion (statement only), Satellites.

8. Properties of Matter

  • Interatomic and intermolecular forces, States of Matter.
  • Solids : Elastic properties, Hooke’s law, Young’s modulus, Bulk modulus, Shear and rigidity modulus.
  • Liquids : Cohesion and Adhesion, Surface tension, Surface energy, Angle of contact, Molecular theory for
  • surface tension, Capillary action. Excess pressure inside a drop and soap bubble, effect of temperature of
  • surface tension.
  • Gases : Kinetic theory of gases, Ideal gas law, Van der Waals equation (Derivation not required).
  • Fluid Dynamics : Streamlined and Turbulent motion, Viscosity, Coefficient of viscosity, Critical velocity,
  • Reynold’s number, Stoke’s law and its derivation using dimensional analysis, Terminal velocity, Bernoulli’s
  • theorem and its applications (Venturi meter, Atomizer, Pitot tube, Dynamic uplift, etc.)

9. Heat and thermodynamics

  • Concept of Heat and temperature, Thermal equilibrium and Zeroth law of thermodynamics, Temperature
  • scales, Thermometers ( Liquid in Glass, Platinum resistance, Constant volume hydrogen gas, thermometer),
  • First law of thermodynamics, Specific heat of an ideal gas at constant volume and constant pressure, relation
  • between them, Thermodynamic state, phase diagrams for H2O and CO2
  • Thermodynamic processes ( reversible and irreversible, isothermal and adiabatic), Carnot cycle, Second law of thermodynamics, efficiency of heat
  • engines. Thermal conductivity determination by Searle’s method, Block body radiation, Wien’s displacement
  • law, Stefan’s law , Newton’s law of cooling.

10. Oscillations

  • Periodic motion, Oscillatory motion. Simple harmonic motion, Kinetic and potential energy in SHM, Simple
  • pendulum, Damped and forced oscillations, Resonance, Composition of SHM in one dimension and two
  • dimensions.

11. Waves and Acoustics

  • progressive wave, equation of a travelling wave, speed of wave on a string. Longitudinal and transverse
  • waves. Superposition of waves. Interference. Stationary wave and Beats. Sound wave in air, displacement
  • and pressure waves, speed of sound-Newton’s formula and Laplace’s correction, Effect of temperature, pressure
  • and humidity of velocity of sound, Laws of transverse vibration of stretched strings. Closed and open organ
  • pipes, Doppler effect, Acoustics of buildings, Characteristics of musical sound, Musical scale, Decibel scale.

12. Universe

  • The constituents of the Universe, Planets-elementary idea about determination of their distances and masses.
  • Starts- brightness, magnitude scale, luminosity, surface temperature, energy source of starts ( concept only).
  • Evolution of the Universe, Cosmic background radiation, Red shift, Hubble’s law, Chandrasekhar limit, White
  • dwarf. Neutron star and Black hole.

13. Ray Optics

  • Refraction at spherical surfaces, thin lens, combination of thin lenses in contact and separated by a distances,
  • effect of silvering one face of a lens. Total internal reflection, optical fibre, rainbow. Optical instruments-simple
  • and compound microscopes, Refracting (Astronomical) and reflecting (Newtonian) Telescopes, Defects of
  • vision and their remedies, Dispersion and deviation of light due to a prism. Dispersive power, dispersion
  • without deviation and deviation without dispersion. Spectrometer and its use for determination of refractive
  • index. Emission and absorption spectra (with suitable examples) Scattering of light by the atmosphere ( blue
  • colour of the sky and the reddish appearance of Sun at sunrise and sunset, derivation not required).

14. Wave Optics

  • Wave front and Huygen’s Principle, Explanation of reflection and refraction of plane wave at plane surfaces
  • using huygen’s principle, Coherent and non-coherent sources of light, interference of light, Young’s doubleslit
  • experiment, Fringe width, Biprism, Diffraction of Light, Diffraction due to single sit, Polarization, Transverse
  • nature of light waves, linearly polarized light. Brewster’s law, Use of Polarized light. Polaroids.

15. Electrostatics

  • Charges and their conservation, charge quantization, Coulomb’s Law, Electric potential and field due to a
  • point charge and dipole in an electric field. Gauss’s theorem and its simple applications ( Field due to an
  • infinite charged cylinder, plane sheet of charge. Charged conducting sheet, hollow conducting sphere, spherical
  • conductor). Conductors and insulators, Concept of polarization and dielectric constant, Electrostatic induction,
  • Capacitance, parallel plate, cylindrical and spherical capacitors, grouping of capacitors, Energy of capacitors,
  • loss of energy due to sharing of charge Van de Graff generator.

16. Current Electricity

  • Concept of Drift velocity and Mobility, Current density and electric current, Ohm’s law, resistivity, conductivity
  • of various materials, zero conductivity and superconductivity (elementary idea). Carbon resistors and their
  • colour code, temperature dependence of resistance, Kirchoff’s current and voltage laws and their simple
  • applications, Whetstone bridge and its application in meter bridge, Principle of Potentiometer and its application
  • for comparison of emf.

17. Thermal and Chemical effect of current

  • Heating effect of current Joule’s law, Thermocouple, elementary idea of Seebeck, peltier and Thomson effect,
  • Faraday’s law of electrolysis and their verification, Dry cell, Lead accumulator, Nickel-cadmium cell, Button
  • cells.

18. Magnetic effect of current

  • Oersted’s experiment. Biot Savart law, magnetic field due to a straight ware and a circular loop carrying
  • current, magnetic field due to a solenoid, Moving coil galvanometer and its conversion in to an ammeter and
  • a voltmeter. Force on a conductor carrying current, torque on a current loop in a magnetic field, force between
  • two parallel conductors carrying current, definition of Ampere.

19. Electromagnetic Induction and Alternating Current

  • Faraday’s and Lenz’s lays self and mutual induction- deduction of coefficients, eddy currents, Induced emf in
  • a coil rotating in a uniform magnetive field. Alternative voltage and current, RMS, Peak and average values of
  • voltage and current Reactance and impedance for L, C and R, Behaviour of circuits with L,C and R (Phasor
  • diagrams only), Power factor, resonant circuits, Q-factor. Electrical machines and devices- transformer, AC
  • Generator, Choke and starter.

20. Magnetism

  • Properties of bar magnets, field and potential due to a magnetic dipole, Current loop as a magnetic dipole,
  • torque on a magnetic dipole placed in a uniform magnetic field lones, Comparison of magnetic fields due to a
  • bar magnet and a solenoid carrying current. Earth’s magnetic field and elementary idea about its origin, Para
  • dia and ferromagnetic substances with examples, Electomagnets and permanent magnets, elementary idea
  • about modern theory of magnetism.

21. Electromagnetic waves (Qualitative treatment)

  • History of electromagnetic waves ( Contributions of Maxwell, Hertz, Bose, Marconi), Electromagnetic spectrum
  • ( radiowaves, microwave infrared, optical, ultraviolet, x-ray and Gamma rays). Simple ideas about their properties
  • and applications.

22. Atomic and Nuclear Physics

  • Discovery of electron, Rutherford scattering experiment, Bohr model of atom, hydrogen spectrum, Photoelectric
  • effect, particle nature of light, Einstein’s photoelectric equation, photocell, matter waves, De Broglie relation.
  • Composition of nucleus, Size of nucleus, atomic number and mass number, mass-energy per nucleon with
  • mass number, Radioactivity, α, β, and γ rays. Simple explanation of α, β, and γ decay. Radioactive decay law,
  • half life and mean life, nature of nuclear forces, nuclear fission and fusion.

23. Semiconductor devices

  • Energy bands in solids, band gap conductors semiconductors and insulators, P-n junction semiconductor
  • diode, diole as a rectifier, solar cell, LED, Junction transistor, transistor action, collector amplifiers ( elementary
  • idea), Logic gates (AND, OR and NOT gates) and combination of gats NAND and NOR), Binary number
  • system and Boolean algebra, Truth table.

24. Basics of Communication (Qualitative treatment)

  • Analog and digital signals and their mutual conversion, Amplitude, Frequency and pulse modulation
  • and their demodulation, Principles of digital transmission and retrieval of information, Fax and Modem.
  • Space communication-Propagation of electromagnetic waves in the atmosphere, Sky and space wave
  • propagation, Satellite communication, Applications in Remote Sensing. Line communication two wire lines,
  • cables, telephone links, Optical communication-optical fibres, Basic principles of Lasers and their applications,
  • elementary principles of light modulation.

DECE LE Math Syllabus

1. Set Theory

  • Sets and their representation, Finite and infinite sets, Empty Set, Equal sets, (Union, Intersection
    and Difference).
  • Application of sets, ordered pairs, Cartesian product of sets, Relations, domain, co-domain and range, function-into and onto functions, One-one into and one-one onto functions, constant functions,
  • Identity functions, composition of functions, Invertible functions, Binary operations.

2. Boolean Algebra

  • Boolean Algebra as an algebraic structure, Principle of duality, Boolean functions,
    conditional and biconditional statements, valid arguments, switching circuits, Applications of Boolean algebra to switching circuits.

3. Mathematical Logic

  • Statements, use of venn diagram in logic, Negation operation. Basic logical connectives
    and compound statements including their negations, Truth tables, Tautology, Duality, Algebra of statements
  • Application of logic in solving simple problems.

4. Algebra

  • complex numbers, representation of complex numbers as points on Agrand Plane, algebra of
    complex numbers, real and imaginary parts, modulus and argument of complex numbers. Triangle inequality,
    Polar representations of complex numbers. Square root of a complex number, cube roots of unit, De-moivre’s
    Theorem with application to find the nth rooth of a complex number.
    Sequence and examples of finite and infinite sequences.

5. Quadratic equations and expressions

  • Revision of “Solutions of Quadratic Equations by factorizations and by using formula, Relations between roots and coefficients, nature of Roots, Formation of Quadratic equations with given roots”.
  • Symmetric functions of roots, equations reducible to quadratic forms, extreme values of quadratic
    expressions in one variable, conditions for resolutions into linear factors of a quadratic expressions in two variables.
  • Permutations and combinations and problems based on them, principle of mathematical Induction
    and simple applications.
  • Binomial theorem : Statements, Proof of Binomial theorem for positive integral index and problems,
    statements only of Binomial theorem for any index, exponentials functions and logarithmic functions

6. Matrices and Determinants

  • Concepts of a matrix, types of matrices, equality of Matrices (only real entries).
  • Addition, scalar multiplication and multiplication of matrices, statements and important results on operations of matrices.
  • Determinants of square matrix, properties of determinants, Minors and cofactors, solving system of linear equations, Transpose, adjoint and inverse of matrix.
  • Consistency and inconsistency of system of a linear equations in 2 and 3 variable using inverse of a matrix.

7. Trigonometry

  • Definition of trigonometric functions, periodic functions, concept of periodic of trigonometric functions, values of trigonometric functions of particular values of x. Compound angles, multiple and submultiple angles, Tansformation formula. Conditional identities.”
  • Graphs of sine, cosine, tangent and their reciprocal functions.
  • General solutions of trigonometrical equations and inverse circular functions.
  • Properties of triangles
  • Logarithms
  • height and distances

8. Two Dimensional co-ordinate Geometry —

  • Cartesian system of co-ordinates, Distance formula, Area of a triangle, conditions of colinearity of 3
    points, section formula, centre locus and in centre locus and its equation.
  • Standard general equation of a straight line, Intersection of Lines, Equations of bisectors of angle
    between two straight lines. Angle between two line, concurrency of 3 lines, distances of a point from a line.
  • Translation and rotation of axes, Equation of family of lines through and intersection of two lines.
    Equation of a circle, general equation of a circle equation of tangent, normal and chord to a circle.
  • Parametric equation of a circle intersection of a circle with a straight line or a circle. Equation of a circle through the points of intersection of two circle and that a circle and straight line. Section of a cone, Equations of the conic sections (Parabola, hyperbola, ellipse in standard forms. Equation of tangent and normal).

9. Calculus

  • Concept of a real function, its domain and range, types of functions and their graphs, Limit of a
    function. Continuity of a function, Intermediate value property of continuous function.
  • Relation between continuity and differentiability, Derivative of some simple functions from first principle.
  • Derivative of a composite function, implicit function, inverse circular functions, Derivatives of functions in parametric form, Derivatives upto order three.
  • dy/dx as a rate measurer, geometrical interpretation of dy/dx. Equation of tangents and normals.
    Increasing and decreasing functions and sign of derivatives, Maxima and minimum, Rollea’s Theorem
    and mean value theorem (without proof). Approximation by differentials, Curve sketching of simple curves.
  • Integrations as the inverse process of the differentiation. Integration by substitution and by parts
    ,partial function and their use in integration rational function.
  • Definite integrals and its simple properties.
  • Definite integrals as the limit of a sum.
  • Determination of area enclosed by standard curves (straight lines, circle, parabolas ellipse)

10. Differential Equations

  • Definition, order and degree, General and particular solution, Formation of differential equations,
  • Solutions of differential equations by variable method. Homogeneous differential equations of first order, Solution of second order differential equations.

11. Vectors

  • vectors and scalars, Types of vector- equal, unit zero, position vector of a point, Local and free
    vectors etc.
  • Components of a vector, Addition of vectors, Multiplication by scalars, scalar and vector products of 2 vectors with their geometrical meaning, scalar and vector-triple products.
  • Application of geometry, Moment of a vector about a line.
  • Coplanarity of three- vector of four points using scalar triple product.

12. Dimensional co-ordinate geometry

  • Co-ordinate axes and co- ordinate planes in 3 dimensional space, coordinates of a point in space .distance between 2 points ,section formula, direction co- sines, and direction ratio of a line joining 2 points, projection of the join of 2 points on a given line.
  • Angle between two lines whose direction cosines are given cartesian and vector equations of a line through (i) a point and parallel to a given
    vector (ii) two points.
  • Collinearity of 3 points , coplanar and skew lines, Shortest distance between 2 linnes, condition of intersection of 2 lines and 2 planes and a plane.
  • Conditions of coplanarity of 2 lines in vector and cartesian from length of perpendicular of a point from a plane by both vectors and cartesian method. Equation of a sphere, its centre, radius, diameter.

13. Statics

  • Statics- Basic concepts of laws of mechanics, and force. Resultant of coplanar, concurrent and parallel forces couples and members, conditions of equilibrium of particle under 3 concurrent forces.

14. Dynamics

  • Dynamics- Basic concepts of displacement, speed , velocity, average speed, uniform velocity uniform
    asseleration, resultant of 2 velocities, motion of a article in a straight line motion under gravity, projectile motion.

15. Probability

  • Probability Random experiments and sample space, events , probability on a discrete sample space, theorems of probability, addition rule multiplication rule, independent and independent events, experiments conditional probability repeated trials.

DECE LE Chemistry Syllabus

PHYSICAL CHEMISTRY

  • Mole concept and related numerical analysis
  • Laws of chemical combination. Mole concept, equivalent weights, atomic weights, molecular weight, eudiometry,
  • problems based on chemical equations.
  • Oxidation-reduction as electron transfer processes, Oxidation numbers, calculation of oxidation numbers,
    balancing of redox equations by oxidation number method and ion-electron method, equivalent weights of
    oxidants and reductants, Roles of K2Cr2O7′ KMnO4 , O3 , H2O2 , SO2 , I2 , FeSO4
  • States of matter
    (A) Gaseous stste, Kinetic theory of gases, equation of state, Grahams law of diffusion, Root Mean
    Square Velocity.
    Graphical distribution of molecular speeds of ideal gases and the effect of temperature, Most probable,
    velocity, average speed, Van der Waals equation and significance of Van der waals constants.
    (B) The liquid state, Properties of liquids, Concept of vapour pressure, surface tension and viscosity
    (C) The Solid State. The crystalline state and types of erystals. Seven crystal systems and 14 Bravais
    lattices, close packing in crystals, fee, ccp and bcc lattices.
  • Atomic structure.
    The Bohr and Sommerfeld models and related calculations, Spectral distribution and the Rydberg constant, deBroglie concept and Heisenberg Uncertainty Principle. The three dimensional atom as in quantum mechanics, Shapes of orbitals, Quantum numbers, Aufbau principle, Hund’s rule, Pauli exclusion principle, electronic configuration of elements, and ions (upto at no.34)
  • Radioactivity.
    Artificial and natural radioactivity,α, β and γ cause of radioactivity disintegration law, group displacement law, half-life period, average life, mass defect, binding energy, balancing of nucleate reactions, Fission and fusion,isotopes and their uses, isobars and isotones.
  • Chemical bonding:
    Octet concept, Types of bond- ionic covalent, coordinate, hydrogen bond ; Vander Waals attractions σ−π and ζ− (tau) bonds, Hybridisation VSEPR theory, dipole moment, resonance, shape of molecules and jons (CH4,NH3, H2O, SO4 , -2 and NO3
  • Concept of molecular orbitals, MO diagrams of some homonuclear and hetronuclear diatomic molecules (H2, H2, N2, CO and NO).
  • Classical concepts, modern concepts (Bronsted-Lowis and SHAB Principles). Salts and their classifications
    pH and pOH, pKa and pKb, relative strengths of acids and bases, buffer solutions.
  • Volumetry
    Standard solutions and primary standards, strength parameter (normality, molarity, molality, %age, mole fraction
    and ppm). Acid-base titration and indicators (phenolphthalein and methyl orange), redox titrationpemanganometry dichrometry, volume strength of H2 O2
    solution.
  • Energetics, Bond energy and enthalpy of reaction, exo and endo-thermic reactions, first law of thermodynamics, internal energy, pressure-volume-works relationships for gases, enthalpy, extensive and intensive, properties of formation, combustion, neutralization, hydrogenation,fusion and vaporization, Resonance energy.
  • Chemical and related equilibria, Law of mass action, equilibrium constant Le Chatelier’s principle, Equilibrium constants of the following reactions- gaseous dissociation of HI, SO3 and PCI5 , Esterification and formation of ammonia. Relation between K and ∆ G.
  • Colligative properties of solutions, Relative lowering of vapour pressure, elevation of boiling point, depression of freezing points, osmotic pressure, ideal and non-ideal solutions, Vant Hoff factor- dissociation and association, Henry’s faw.
  • Chemical Kinetics. Rate of chemical reactions, factors affecting rate of reactions, molecularity and order of reactions, rate constants of first order reaction and its characteristics, temperature dependence of rate constant Arrhenius equation.
  • Electrochemistry. Faraday’s law, Electrolytic conductance- specific, equivalent and molar conductivities, kohalarausch’s law, Electrochemical cells and their cell reactions. Electrode potential, electrochemical series, simple calculations based on emf of galvanic cells.
  • Surface chemistry, Elementary idea of adsorption (excluding isotherms), Colloids and their types, Properties
    of colloids, elementary concepts of emulsions, surfactants and micelles.

DECE LE INORGANIC CHEMISTRY Syllabus

  • Periodicity of elements.
    The long periodic table, classification of elements in terms of s,p, d and f meteoroids, periodicity and enthalpy of ionization, electron affinity and electronegativty.
  • Transition elements.
    3d series only. General characteristics, Oxidation states and their stability colur, magnetic properties, complexing properties and catalytic properties.
  • Metallurgy, Ores and minerals, gaugue, flux and slag.
    Commonly occurring ores of iron, copper, lead, magnesium, aluminium, mercury, zinc, silver, gold and tin. General principles and reactions involved in carbon reduction (Fe and Sn), self reduction methods (Cu and Pb), electrolytic reduction method (Al and Mg), cyanide process (Ag and au).
  • Chemistry of non metals and their compounds.
    Carbon- oxides, carbides, halides, fluorene, Industrial fuels, calorific value of fuels, Nitrogen- N2, NH2
    and HNO3, phosphourous- PH3 oxides, orthometer and pyro-oxy-acis. Sulphur SO2 , H2 S, H2
    SO4 (contact process only), Halogens- Hydrides, oxides and oxyacids, Inter-halogens. Noble gases, Isolation and fluorides of Xe.
  • Principles of qualitative analysis –
    Systematic grouping of cations and related group reagents, test for anions (other than fluorides,phosphates,silicates and borates)
  • Preparation of important compounds and their uses, NaOH, Na, CO3 10H2O. Ca (OCI) Cl. Ca (OH)2
    , MgSO4, 7H2O, CuSO4, 5H2O, FeSO4 , 7H2O, ZnSO4 , 7H2O, AgNO3 , KMnO4 , K2Cr2O, Mohrs salt, potash alum, plaster of Paris, calomel, corrosive sublimate, vermillion and nesslers reagent.
  • Fertilizers – nitrogen and phosphorous containing
  • Pollution – water and air.

DECE LE ORGANIC CHEMISTRY SYLLABUS

  • Fundamentals. Hybridisation of carbon, structural formulae of organic compounds. Catenation, spatial arrangements around sp3, sp2 hybridised carbon atoms, Homologous series and classification of organic compounds, functional groups, nomenclature (IUPAC) of hydrocarbons, mono-and bi-functional group containing compounds. Physical properties of organic, compounds – boiling. pt, melting pt, solubility and density.
  • Isomerism – structural including keto-enol tautomerism, confirmation of ethane and butane- Newmann’s projection only. geometrical isomerism – cis and trans, optical isomerism with reference to one and two stereo-geinc centres (RS nomenclature not required).
  • General concept – of Organic reactions. Fission of bonds. reaction intermediates- carbocations, free radicals and carbanions, acidity and basicity due to inductive and resonance effects, Nucleophiles and electrophiles, types of organic reactions-addition substitution and elimination.
  • Principle – involved in the preparation of organic compounds and related chemical reactions.
    (a) Alkanes – from unsaturated hydrocarbons, alkyl halides and carboxylic acids, combustion and monohalogenation of alkanes, cracking and refining of petroleum, octane number.
    (b) Alkenes – Form alkyl halides and alcohols, their chemical reactions with Cl2
    ,aqueous acis, quos KMnO4 ozone and boron hydride Markownikoff and anti-markinokoff addition, hydrogenation of alkenes.
    (c) Alkynes- from metal acetylide and halogen derivatives, reduction, some electrophilic additions, acidity of acetylene.
    (d) Halogen derivatives of alkanes – form alcohol, alkynes and alkynes, Chloroform, haloform reactions, nucleophilic substitution and elimination reaction in monohalogen derivatives, an elementary treatment of Grignard reagent. (e) Alcohol – from alkyl halides, aldehydes’ and ketones, Reactions of alcohols-oxidation esterification, dehydration and reaction with PCl5
    (f) Ether- form alkyl halide and alcohol. Reactions Hl, PCL5 and acetyl chloride.
    (g) Aldehydes and ketones – from alcohol, alkynes, carboxylic acid salts, Reactions with hydroxylamine,
    phenyl hydrazine, Tollens reagent, Aldol condensation, Prekin reaction Canizzaro reaction and Benzoin
    condensation.
    (h) Carboxylic acids and their derivatives- from cyanides alcohos and esters. reactions with PCl5
    alcohol
    ammonia, Rosenmund’s reduction.
    (h) Carbosylic acids and their derivatives- from cyanides alcohols and esters. Reactions with PCl5
    alcohol ammonia, Rosenmund’s reduction.
    (i) Aromatic compounds – aromaticity, benzene, phenol and aniline, Diazo coupling.
  • Polymer – natural and synthetic- rubber, polythene, PVC, polyester, techniques of polymerisation.

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